アカイ ショウジ   Akai Shoji
  赤井 昭二
   所属   栄養学部
   職種   教授
言語種別 英語
発行・発表の年月 1999/05
形態種別 研究論文
査読 査読あり
標題 Crystal Structure of Potential Key Compounds, DL-(1,2,3',4,5,6'/3,6)-6-Azido-5'-O-t-butyldiphenylsilyl-6-(cyano)hydroxymethyl-3,5-di-C-hydroxymethyl-1,2:3,3'-di-O-isopropylidore-4-O-methoxymethyl-1,2,3,4-cyclohexanetetrol toward Tetrodotoxin
執筆形態 共著
掲載誌名 Analysical Sciences
掲載区分国外
出版社・発行元 The Japan Society for Analytical Chemistry
巻・号・頁 15(5),pp.503-504
著者・共著者 S. Akai, N. Sugita, J. Yoshimura, K.-i. Sato
概要 The title compd. is monoclinic, space group Cc, with a 13.678(4), b 16.941(3), c 17.499(3)Å, 130.49(2)°; dc = 1.194, Z = 4, R = 0.037, Rw = 0.042 for 2334 reflections. At. coordinates are given. The conformation of the 6-membered ring is chair form and the configuration at 6' position is the same (s) as that of natural tetrodotoxin. The D- and L-mols. are linked alternately along the c-axis by H bonding.