アカイ ショウジ   Akai Shoji
  赤井 昭二
   所属   栄養学部
   職種   教授
言語種別 英語
発行・発表の年月 2001/05
形態種別 研究論文
査読 査読あり
標題 Novel Methods for synthesizing 2-Chloroaldehyde from Carbonyl Compounds and Converting It into 2-Hydroxyaldehyde Derivatives
執筆形態 共著
掲載誌名 Tetrahedron Lett.
掲載区分国外
出版社・発行元 Elsevier
巻・号・頁 42(21),pp.3625-3628
著者・共著者 K. Sato, T. Sekiguchi, S. Akai
概要 2-Chloroaldehyde derivs. were synthesized from carbonyl compds. with [chloromethyl (dimethyl)sulfonium trifluoromethanesulfonate,] and DBU in THF in good yields. Further, 2-chloroaldehyde derivs. were converted into the corresponding 2-hydroxyaldehydes by treating the derivs. with n-Bu4NOH in good yields with the inverted configuration. The stereochem. of all the products were detd. by NMR (NOE).